New PDF release: Advances in Carbohydrate Chemistry and Biochemistry 47

By R. Stuart Tipson and Derek Horton (Eds.)

ISBN-10: 0120072475

ISBN-13: 9780120072477

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Im Similar results were ~btained'~' with 3-deoxy-~-manno-2-octulosonicacid (KDO). 132 This short discussion illustrates that there is still much to be learnt about the complexing behavior of acidic polysaccharides. IV. APPLICATIONS 1. l I Tables of Mi values in buffered calcium acetate as s u p porting electrolyte have been published for some 150 carbohydrates(cyclitols, sugars, and methyl glycosides,l 3 alditols,48 and anhydrohe~osesl~). Some typical values are shown in Table V. c. c. they move rapidly and produce more diffuse spots.

Rees, and W. E. Scott, J. Chem. 2, (1975) 237 -240; S. Thanomkul, J. A. Hjortas, and H. ,Sect. B, 32 (1976) 920-924. (123) R. Kohn, PureAppl. , 42 (1975) 371-397. (124) G. T. Grant, E. R. Moms, D. A. Rees, P. J. C. Smith, and D. , 32 (1973) 195-198. (125) A. Haug and 0. Smidsrd, Acta Chem. , 24 (1970) 843-854. 34 STEPHEN J. ANGYAL The reason for this differencein binding strength may lie in the ability of S? and Ba2+to coordinate with a greater number of oxygen atoms in poly(guluronate) than in poly(galacturonate).

Thom, and J. K. Madden, in G. 0. ),The Polysaccharides, Vol. 1, Academic Press, New York, 1982, pp. I95 -290. ( 1 10) R. 0. Gould and A. F. Rankin, Chem. , (1970) 489-490. (1 1 I ) C. A. M. Vijberg, J. A. Peters, A. P. G. Kieboom, and H. van Bekkum, Tetrahedron, 42 (1986) 167-174. (1 12) W. J. Cook and C. E. , Sect. B, 29 (1973) 215-222. (1 13) S. Furberg and S. Helland, Acta Chem. , 16 (1962) 2373-2383. ( 1 14) N. C. Panagiotopoulos, G. A. Jeffrey, S. J. La Placa, and W. C. Hamilton, Acfa Crysfallogr..

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Advances in Carbohydrate Chemistry and Biochemistry 47 by R. Stuart Tipson and Derek Horton (Eds.)


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