By R. Přibil, R. Belcher, H. Freiser
Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This publication additionally considers the “passive” function of those ingredients, that's, their screening (masking) houses, which significantly increase the selectivity of the reactions in universal use.
This textual content contains six chapters prepared into sections. the 1st half offers with the makes use of of EDTA and its derivatives in a few fields of chemical research. After offering an outline of the historical past in the back of the advance of EDTA as an analytical reagent, this publication discusses to the character of equilibria of complexes and the equipment utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions via natural reagents. The bankruptcy on colorimetry encompasses a part on “colored complexing agents,” that are used additionally in colorimetric determinations of a few components. this article concludes by way of comparing using EDTA as a covering agent in colorimetry.
This e-book could be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.
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Extra resources for Analytical Applications of EDTA and Related Compounds
9 . COOK, C . M . and L O N G , F . Α . , J. Am. Chem. Soc. 7 3 , 4 1 1 9 ( 1 9 5 1 ) . 1 0 . MARTELL, A. , / . Chem. Educ. 2 9 , 2 7 0 ( 1 9 5 2 ) . 1 1 . PLUMB, R . C , MARTELL, A . E. and BERSWORTH, F . C , / . Am. Chem. Soc. 5 4 , 1 2 0 8 ( 1 9 5 0 ) . 12. SCHWARZENBACH, G . , Helv. chim. acta 3 2 , 8 3 9 ( 1 9 4 9 ) . 1 3 . H t o r r z , W . , Liebigs Ann. Chem. 122, 2 5 6 ( 1 8 6 2 ) . 14. LÜDECKE, W . , Liebigs Ann. Chem. 1 4 7 , 2 7 2 ( 1 8 6 8 ) . 1 5 . E s c H W E n x R , H . , Liebigs Ann.
E. to a substitution of the coordinated water by the hydroxyl ion, and thus to an alteration of the coordination sphere of the ion (see Fig. 17). The bydroxo complex is blue. t 8 c -I'O ν V 300 400 500 600 700 Wavelength (nm) F I G . 17. HjO, (b) = 8-91 X 10"^ Μ NajCrYOH. 1 . 0 0 2 cm cell. ) (g) Determination of the stability constant with the aid of radioactive indicators  The concentration of the free metal ions present in the solution of the complex can be determined by the radioactive isotope method.
Acta 2 9 , 3 6 4 ( 1 9 4 6 ) . 3 7 . SCHWARZENBACH, G . , KAMPFTSCH, E . and STED^ÍER, R . , Helv. chim. acta 2 8 , 1 1 3 3 ( 1 9 4 5 ) . 3 8 . , COURTNEY, R . C . and MARTELL, A . , / . Am. Chem. Soc. 7 4 , 5 0 5 7 ( 1 9 5 2 ) . 3 9 . , COURTNEY, R . C . and MARTELL, A. , / . Am. Chem. Soc. 7 5 , 2 1 8 5 ( 1 9 5 3 ) . 4 0 . TOREN, P . E. and KOLTHOFF, I . , / . Am, Chem. Soc. 7 7 , 2 0 6 1 ( 1 9 5 5 ) . 4 1 . Brit. Patent 4 9 6 , 7 8 1 . 4 2 . U . S . Patent 2 , 4 0 7 , 6 4 5 . 4 3 . U . S . Patent 2 , 1 0 3 , 5 0 5 .
Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser